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oai:ebyu-rdlopen.rawdatalibrary.net:ebyu/124122026-10-18T21:13:21Zopenairedrivercom_ebyu_10000col_ebyu_10001

Crystal structure and Hirshfeld surface analysis of isopropyl 4-[2-fluoro-5-(trifluoromethyl)phenyl]-2,6,6-trimethyl-5-oxo-1,4,5,6,7,8-hexahydro-quinoline-3-carboxylateYıldırım, Sema ÖztürkAkkurt, MehmetÇetin, GökalpŞimşek, RahimeButcher, Ray J.Bhattarai, Ajaya1,4-dihydropyridine ringcrystal structurecyclohexene ringHirshfeld surface analysisquinoline ring systemvan der Waals interactionsIn the title compound, C23H25F4NO3, the 1,4-dihydropyridine ring adopts a distorted boat conformation, while the cyclohexene ring is almost showing a half-chair conformation. In the crystal, intermolecular N—H· · ·O hydrogen bonds connect the molecules into chains with graph-set motif C(6) parallel to the a-axis. These chains are linked together by C—H· · ·O and C—H· · ·F interactions, forming a three-dimensional network. In addition, C—H· · ·π interactions link the molecules into layers parallel to the (100) plane. A Hirshfeld surface analysis was performed to further investigate the intermolecular interactions. © 2023 International Union of Crystallography. All rights reserved.International Union of Crystallography2023Articlehttps://rdlopen.rawdatalibrary.net/r/ebyu/12412https://doi.org/10.1107/s205698902300141x2056-9890enActa Crystallographica Section E: Crystallographic Communicationsinfo:eu-repo/semantics/openAccessinfo:eu-repo/semantics/articlehttps://ebyu-rdlopen.rawdatalibrary.net/tr/items/ebyu/12412