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oai:ebyu-rdlopen.rawdatalibrary.net:ebyu/127592026-10-18T20:43:10Zopenairedrivercom_ebyu_10000col_ebyu_10001

Synthesis, electrochemical and spectroscopic properties of ferrocene-based compoundsTaşkor Önel, GülceÖzgül Karaaslan, EmineÖsken, İpekSaygılı, NezireCross-couplingCyclic voltammetryFerrocene derivativesPalladium catalystUV–vis spectroscopyFerrocene derivatives have been synthesized by the Suzuki cross-coupling reaction of ferroceneboronic acid with various aryl/heteroaryl halides. The reactions yield ferrocenyl derivatives with overall yields varying between 35 and 98%. The derivatives have been characterized by 1H NMR, 13C NMR, IR, HRMS and elemental analysis. The structure–property relationship has been investigated based on UV/Vis spectroscopy and cyclic voltammetry. Cyclic voltammetry studies revealed when the side group of ferrocenes were an electron-donating, lower oxidation was displayed. On the other hand, the strong electron-withdrawing group had a higher oxidation potential. Graphical abstract: [Figure not available: see fulltext.] © 2021, Institute of Chemistry, Slovak Academy of Sciences.Springer Science and Business Media Deutschland GmbH2022Articlehttps://rdlopen.rawdatalibrary.net/r/ebyu/12759https://doi.org/10.1007/s11696-021-02034-70366-6352enChemical Papersinfo:eu-repo/semantics/openAccessinfo:eu-repo/semantics/articlehttps://ebyu-rdlopen.rawdatalibrary.net/tr/items/ebyu/12759