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oai:ebyu-rdlopen.rawdatalibrary.net:ebyu/147472026-10-18T20:36:35Zopenairedrivercom_ebyu_10000col_ebyu_10001

Singlet oxygen generation from poly[4-diacetoxyiodo]styrene and hydrogen peroxideÇatir, MustafaHydrogen tetroxideOxidationPeroxyiodanePolymer-supported hypervalent iodineSinglet oxygenTreatment of hydrogen peroxide with a polymer-supported hypervalent iodine compound, poly[4-diacetoxyiodo] styrene (PDAIS), generates singlet molecular oxygen (1O2). Singlet oxygen generation was proved by trapping with typical organic compounds such as conjugated dienes, aromatic dienes, and electron-rich alkene. When compared to monomer analogue, the use of PDAIS in peroxidation of substrates gave slightly better yields (45%–96%). Regeneration and reuse of PDAIS showed similar activity. The mechanism underlying generation of singlet oxygen and reaction scope was examined. © TÜBITAK.TUBITAK2017Articlehttps://rdlopen.rawdatalibrary.net/r/ebyu/14747https://doi.org/10.3906/kim-1602-131300-0527enTurkish Journal of Chemistryinfo:eu-repo/semantics/openAccessinfo:eu-repo/semantics/articlehttps://ebyu-rdlopen.rawdatalibrary.net/tr/items/ebyu/14747