Construction of a novel Cu(II)-selective electrode with long life span based on 8-aminoquinoline functionalized bentonite
Özet
A novel 8-aminoquinoline-functionalized bentonite was utilized as an electroactive sensing element in the construction of a potentiometric carboxylated-PVC-based polymeric membrane electrode. The electrode exhibited a linear response for copper(II) ions in the concentration range of 1.0 × 10–5−1.0 × 10–2 mol/dm3 with a slope of 28.24 mV/decade. While the response time of the electrode determined as about 20 s, its detection limit and long life time was determined as 5.0 × 10–6 mol/dm3 and 5 months, respectively. The proposed electrode was applied for the potentiometric detection of Cu(II) contents of some spiked water samples and satisfied results were attained. Graphical abstract: [Figure not available: see fulltext.] © 2022, Springer-Verlag GmbH Austria, part of Springer Nature.
Anahtar Kelimeler
Tam Kayıt
| Alan | Değer | Dil |
|---|---|---|
| dc.contributor.author | Dogan, Bilge | |
| dc.contributor.author | Coldur, Fatih | |
| dc.contributor.author | Caglar, Bulent | |
| dc.contributor.author | Ozdemir, Agah Oktay | |
| dc.contributor.author | Guner, Eda Keles | |
| dc.contributor.author | Ozdokur, Kemal Volkan | |
| dc.date.accessioned | 2026-10-18T20:27:16.202857566Z | |
| dc.date.available | 2026-10-18T20:27:16.202857566Z | |
| dc.date.issued | 2023 | |
| dc.description.abstract | A novel 8-aminoquinoline-functionalized bentonite was utilized as an electroactive sensing element in the construction of a potentiometric carboxylated-PVC-based polymeric membrane electrode. The electrode exhibited a linear response for copper(II) ions in the concentration range of 1.0 × 10–5−1.0 × 10–2 mol/dm3 with a slope of 28.24 mV/decade. While the response time of the electrode determined as about 20 s, its detection limit and long life time was determined as 5.0 × 10–6 mol/dm3 and 5 months, respectively. The proposed electrode was applied for the potentiometric detection of Cu(II) contents of some spiked water samples and satisfied results were attained. Graphical abstract: [Figure not available: see fulltext.] © 2022, Springer-Verlag GmbH Austria, part of Springer Nature. | |
| dc.description.sponsorship | The authors gratefully acknowledge funding support from Erzincan Binali Yildirim University, The Scientific Research Projects Coordination Unit (FBA-2020-687). | |
| dc.identifier.doi | 10.1007/s00706-022-03008-5 | |
| dc.identifier.eissn | 1434-4475 | |
| dc.identifier.endpage | 64 | |
| dc.identifier.issn | 0026-9247 | |
| dc.identifier.issue | 1 | |
| dc.identifier.scopus | 2-s2.0-85143130387 | |
| dc.identifier.startpage | 53 | |
| dc.identifier.uri | https://rdlopen.rawdatalibrary.net/r/ebyu/12359 | |
| dc.identifier.volume | 154 | |
| dc.identifier.wos | WOS:000912834500002 | |
| dc.language.iso | en | |
| dc.publisher | Springer | |
| dc.relation.ispartof | Monatshefte fur Chemie | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.subject | 8-Aminoquinoline | |
| dc.subject | Carboxylated PVC | |
| dc.subject | Copper(II) detection | |
| dc.subject | Functionalized-bentonite | |
| dc.subject | Potentiometric electrode | |
| dc.title | Construction of a novel Cu(II)-selective electrode with long life span based on 8-aminoquinoline functionalized bentonite | |
| dc.type | Article | |
| dspace.entity.type | Publication | |
| rdl.citation.scopus | 5 | |
| rdl.citation.wos | 3 | |
| rdl.source.index | SCOPUS | |
| rdl.source.index | WOS | |
| rdl.wos.index | Science Citation Index Expanded (SCI-EXPANDED) |
