Yilmaz, Erkan; Yavuz, Emre

Since the discovery of graphene, nano-sized two-dimensional (2D) transition metal dichalcogenides (TMDs) such as MoS2, MoSe2, MoTe2, NbS2, NbSe2, WS2, WSe2, TaS2 and TaSe2, which have been classified as next-generation nanomaterials resembling graphene (G) have complementary basic properties with those of graphene in terms of their practical applications. TMDs are attracting great attention due to their attractive physical, chemical and electronic properties. Despite being overshadowed by graphene in terms of frequency of use, TMDs have been used frequently in many areas in recent years instead of carbon-based materials such as graphene (G), graphene oxide (GO), carbon nanotubes (CNTs) and nanodiamonds (NDs). It is seen that the first and frequent uses of TMDs, which are classified as new generation materials, are in the fields of catalysis, electronic applications, hydrogen production processes and energy storage, but it has been used as an adsorbent in sample preparation techniques in recent years. Similar to graphene, layers of TMDs are held together by weak van der Waals interactions. The sandwiched layers of TMDs provide sufficient and effective interlayer spaces so that foreign molecules, ions and atoms can easily enter these spaces between the layers. Intermolecular interactions increase with the entry of different materials into these spaces, and thus, high activity, adsorption capacity and efficiency are obtained in adsorption-based analytical sample preparation methods. Although there are about 35 research articles using TMDs, which are classified as promising materials in analytical sample preparation techniques, no review studies have been found. This review, which was designed with this awareness, contains important informations on the properties of metal dichalcogenides, their production methods and their use in analytical sample preparation techniques.

Yavuz, Emre; Sakir, Menekse; Onses, M. Serdar; Salem, Samaa; Yilmaz, Erkan

Surface Enhanced Raman Spectroscopy (SERS) technique is an effective analytical technique in which fingerprint information about analytes can be obtained, can provide detection limit performance at the single molecule level, and analyzes are performed in a single step without any intermediate steps. SERS technique offers additional benefits rather than other analytical techniques including high selectivity, ultrasensitive detection, uncomplicated protocols, in situ sampling, on-set capability and cost-effectiveness. As a result of the combination of developments in materials and nanotechnology science with the SERS analysis technique, this technique strengthens its use advantage day by day. The most important factor that limited the use of this technique was the fact that the solution containing the desired analyte(s) was dropped onto the SERS substrate and the same substrate could not be reused in subsequent analyses. To solve this problem, scientists have focused on developing reusable SERS substrates in recent years. In these studies, scientists basically used three SERS substrate cleaning applications (1) washing the SERS substrate with a suitable solvent that can elute the analyte from SERS surface after analysis, (2) cleaning the SERS substrate with catalytic degradation of analytes after analysis by modifying them with catalytic active materials and (3) Applying plasma cleaning procedure to SERS substrate after analysis and (4) applying adsorption and desorption procedure prior to SERS analysis. Herein, the aim of this review article is to evaluate the reusable SERS substrates-based methods based on their level of development and their potential to recycle. This review offers a coherent discussion on a wide range of sensing schemes employed in fabricating the SERS substrates. We utilized a critical approach in which elaborative examples were selected to highlight key shortcomings of various experimental configurations. In the same vein, there is a discussion of the advantages and limitations concerning the key instrumental advances and the expansion of the recent methods developed in this area.

Topcu, Cihan

A novel polyvinyl chloride membrane chlorate (ClO3−) selective electrode based on modified smectite was developed for the direct determination of chlorate ions and the potentiometric performance characteristics of its were examined. The best selectivity and sensitivity for chlorate ions were obtained for the electrode membrane containing ionophore/polyvinylchloride/o-nitrophenyloctylether in composition of 12/28/60 (w/w%). The proposed electrode showed a Nernstian response toward chlorate ions at pH=7 in the concentration range of 1×10−7–1×10−1 M and the limit of detection was calculated as 9×10−8 M from the constructed response plot. The linear slope of the electrode was −61±1 mV decade−1 for chlorate activity in the mentioned linear working range. The selectivity coefficients were calculated according to both the matched potential method and the separate solution method. The calculated selectivity coefficients showed that the electrode performed excellent selectivity for chlorate ions. The potentiometric response of electrode toward chlorate ions was found to be highly reproducible. The electrode potential was stable between pH=4–10 and it had a dynamic response time of <5 s. The potentiometric behavior of the electrode in partial non-aqueous medium was also investigated and the obtained results (up to 5% (v/v) alcohol) were satisfactory. The proposed electrode was used during 15 weeks without any significant change in its potential response. Additionally, the electrode was very useful in water analysis studies such as dam water, river water, tap water, and swimming pool water where the direct determination of chlorate ions was required.