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Synthesis, electrochemical and spectroscopic properties of ferrocene-based compounds

ArticleAçık Erişim

Özet

Ferrocene derivatives have been synthesized by the Suzuki cross-coupling reaction of ferroceneboronic acid with various aryl/heteroaryl halides. The reactions yield ferrocenyl derivatives with overall yields varying between 35 and 98%. The derivatives have been characterized by 1H NMR, 13C NMR, IR, HRMS and elemental analysis. The structure–property relationship has been investigated based on UV/Vis spectroscopy and cyclic voltammetry. Cyclic voltammetry studies revealed when the side group of ferrocenes were an electron-donating, lower oxidation was displayed. On the other hand, the strong electron-withdrawing group had a higher oxidation potential. Graphical abstract: [Figure not available: see fulltext.] © 2021, Institute of Chemistry, Slovak Academy of Sciences.

Anahtar Kelimeler

Cross-couplingCyclic voltammetryFerrocene derivativesPalladium catalystUV–vis spectroscopy
RDL Kalıcı Bağlantı (PID)
https://rdlopen.rawdatalibrary.net/r/ebyu/12759Resmi atıflarda kullanılan kalıcı adres
DOI
https://doi.org/10.1007/s11696-021-02034-7Yayıncı resmi DOI adresi
Tam Kayıt
AlanDeğerDil
dc.contributor.authorTaşkor Önel, Gülce
dc.contributor.authorÖzgül Karaaslan, Emine
dc.contributor.authorÖsken, İpek
dc.contributor.authorSaygılı, Nezire
dc.date.accessioned2026-10-18T20:27:37.575066547Z
dc.date.available2026-10-18T20:27:37.575066547Z
dc.date.issued2022
dc.description.abstractFerrocene derivatives have been synthesized by the Suzuki cross-coupling reaction of ferroceneboronic acid with various aryl/heteroaryl halides. The reactions yield ferrocenyl derivatives with overall yields varying between 35 and 98%. The derivatives have been characterized by 1H NMR, 13C NMR, IR, HRMS and elemental analysis. The structure–property relationship has been investigated based on UV/Vis spectroscopy and cyclic voltammetry. Cyclic voltammetry studies revealed when the side group of ferrocenes were an electron-donating, lower oxidation was displayed. On the other hand, the strong electron-withdrawing group had a higher oxidation potential. Graphical abstract: [Figure not available: see fulltext.] © 2021, Institute of Chemistry, Slovak Academy of Sciences.
dc.description.sponsorshipThis research was supported by Hacettepe University (BAP-2013, 013 D09 301 002).
dc.identifier.doi10.1007/s11696-021-02034-7
dc.identifier.eissn2585-7290
dc.identifier.endpage2257
dc.identifier.issn0366-6352
dc.identifier.issue4
dc.identifier.scopus2-s2.0-85123821354
dc.identifier.startpage2249
dc.identifier.urihttps://rdlopen.rawdatalibrary.net/r/ebyu/12759
dc.identifier.volume76
dc.identifier.wosWOS:000754649900004
dc.language.isoen
dc.publisherSpringer Science and Business Media Deutschland GmbH
dc.relation.ispartofChemical Papers
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectCross-coupling
dc.subjectCyclic voltammetry
dc.subjectFerrocene derivatives
dc.subjectPalladium catalyst
dc.subjectUV–vis spectroscopy
dc.titleSynthesis, electrochemical and spectroscopic properties of ferrocene-based compounds
dc.typeArticle
dspace.entity.typePublication
rdl.citation.scopus2
rdl.citation.wos2
rdl.source.indexSCOPUS
rdl.source.indexWOS
rdl.wos.indexScience Citation Index Expanded (SCI-EXPANDED)