Erzincan Binali Yıldırım ÜniversitesiErzincan Binali Yıldırım ÜniversitesiAçık Erişim Arşivi · RDL Open

Generation of singlet oxygen (1O2) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents

Conference ObjectAçık Erişim

Özet

A novel method for the production of singlet oxygen from H 2O2 was developed. A combination of iodoarene (ArI), methyltrioxorhenium (MTO), and H2O2 in the presence of pyridine as the co-catalyst efficiently produced singlet molecular oxygen ( 1O2) under biphasic conditions. The existence of 1O2 was demonstrated by trapping experiments with aromatic dienes, 1,3-cyclodienes, and alkenes. The mechanism of 1O 2 production from the iodoarene/MTO/35 % H2O2 system and the reaction scope was also discussed. © 2014 IUPAC & De Gruyter Berlin/Boston 2014.

Anahtar Kelimeler

catalysisChemical Synthesishomogeneous catalysishypervalent compoundsIUPAC Congress-44oxidationoxygenoxygenationperoxidesradicalssinglet oxygenReaction kineticsRhenium compoundsSynthesis (chemical)
RDL Kalıcı Bağlantı (PID)
https://rdlopen.rawdatalibrary.net/r/ebyu/15092Resmi atıflarda kullanılan kalıcı adres
DOI
https://doi.org/10.1515/pac-2013-0812Yayıncı resmi DOI adresi
Tam Kayıt
AlanDeğerDil
dc.contributor.authorKalay, Erbay
dc.contributor.authorKiliç, Hamdullah
dc.contributor.authorCatir, Mustafa
dc.contributor.authorCakici, Murat
dc.contributor.authorKazaz, Cavit
dc.date.accessioned2026-10-18T20:29:52.968359263Z
dc.date.available2026-10-18T20:29:52.968359263Z
dc.date.issued2014
dc.description.abstractA novel method for the production of singlet oxygen from H 2O2 was developed. A combination of iodoarene (ArI), methyltrioxorhenium (MTO), and H2O2 in the presence of pyridine as the co-catalyst efficiently produced singlet molecular oxygen ( 1O2) under biphasic conditions. The existence of 1O2 was demonstrated by trapping experiments with aromatic dienes, 1,3-cyclodienes, and alkenes. The mechanism of 1O 2 production from the iodoarene/MTO/35 % H2O2 system and the reaction scope was also discussed. © 2014 IUPAC & De Gruyter Berlin/Boston 2014.
dc.description.sponsorshipAcknowledgments: Financial support by the Scientific and Technological Research Council of Turkey (TUBI-TAK) (TBAG-109T161) is gratefully acknowledged.
dc.identifier.doi10.1515/pac-2013-0812
dc.identifier.eissn1365-3075
dc.identifier.endpage952
dc.identifier.issn0033-4545
dc.identifier.issue6
dc.identifier.scopus2-s2.0-84902248571
dc.identifier.startpage945
dc.identifier.urihttps://rdlopen.rawdatalibrary.net/r/ebyu/15092
dc.identifier.volume86
dc.identifier.wosWOS:000339873600008
dc.language.isoen
dc.publisherWalter de Gruyter GmbH
dc.relation.ispartofPure and Applied Chemistry
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectcatalysis
dc.subjectChemical Synthesis
dc.subjecthomogeneous catalysis
dc.subjecthypervalent compounds
dc.subjectIUPAC Congress-44
dc.subjectoxidation
dc.subjectoxygen
dc.subjectoxygenation
dc.subjectperoxides
dc.subjectradicals
dc.subjectsinglet oxygen
dc.subjectReaction kinetics
dc.subjectRhenium compounds
dc.subjectSynthesis (chemical)
dc.titleGeneration of singlet oxygen (1O2) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents
dc.typeConference Object
dspace.entity.typePublication
rdl.citation.scopus13
rdl.citation.wos11
rdl.oa.statusopen
rdl.source.indexSCOPUS
rdl.source.indexWOS
rdl.wos.indexScience Citation Index Expanded (SCI-EXPANDED)
rdl.wos.indexConference Proceedings Citation Index - Science (CPCI-S)