Electrochemical performance of Fe2Al1-xB2 MBene as a novel electrode material for supercapacitor applications

The growing global demand for efficient and sustainable energy storage systems has intensified the need for advanced electrode materials with superior performance and stability. This study focuses on the synthesis and characterization of Fe2AlB2 MAB phase and Fe2Al1-xB2 MBene, highlighting their potential for energy storage applications. The Fe2AlB2 MAB phase was synthesized using FeB and Al powders via high-temperature sintering (1200 °C for 2 h), followed by selective etching of aluminum layers with a 2 M HCl solution to produce Fe2Al1-xB2 MBene. Electrochemical measurements demonstrated that Fe2Al1-xB2 MBene exhibits excellent pseudocapacitive behavior, achieving a specific capacitance of 276 F g−1 at 0.5 A g−1 in a three-electrode system. An asymmetric supercapacitor (ASC) configuration achieved an energy density of 20.6 Wh kg−1 at a power density of 306.4 W kg−1, with 96 % capacitance retention after 10,000 cycles. This research represents one of the pioneering studies on Fe2Al1-xB2 MBene, emphasizing its potential as a high-performance electrode material for next-generation energy storage devices. The findings provide valuable insights into the design and application of 2D MBenes for energy-related technologies. © 2025