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Chemical Effect Analyses of 3d Elements by Study of X-Ray Fluorescence Spectra

ArticleAçık Erişim

Özet

Spectra of K X-rays emitted from pure 3d transition metals and their oxide and sulfate compounds were measured using a single crystal wavelength dispersive X-ray spectroscopy (WDXRF). The measurements were performed using a ZSX-100e sequential spectrometer equipped with an Rh X-ray tube operated. An accurate analytical representation of each line was obtained by a fit to a Lorentz function. The spectra were analyzed in order to examine the K X-ray peak parameters such as asymmetry index, peak energy and relative intensity ratios. The energy shifts and relative intensities weredetermined tobetter understand the chemical effect. © 2018, Peking University Press. All right reserved.

Anahtar Kelimeler

Asymmetry indexChemical effectRelative intensity ratioWavelength dispersive X-ray spectroscopy (WDXRF)Rhodium metallographySingle crystalsSpectrometersSulfur compoundsTransition metal compoundsTransition metalsX ray spectroscopyX ray tubes3d transition metalsEnergy shiftLorentz functionsRelative intensityWavelength dispersive X-ray spectroscopiesX ray fluorescenceChemical analysis
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AlanDeğerDil
dc.contributor.authorDurdaği, Sevil(Porikli)
dc.date.accessioned2026-10-18T20:28:57.700508510Z
dc.date.available2026-10-18T20:28:57.700508510Z
dc.date.issued2018
dc.description.abstractSpectra of K X-rays emitted from pure 3d transition metals and their oxide and sulfate compounds were measured using a single crystal wavelength dispersive X-ray spectroscopy (WDXRF). The measurements were performed using a ZSX-100e sequential spectrometer equipped with an Rh X-ray tube operated. An accurate analytical representation of each line was obtained by a fit to a Lorentz function. The spectra were analyzed in order to examine the K X-ray peak parameters such as asymmetry index, peak energy and relative intensity ratios. The energy shifts and relative intensities weredetermined tobetter understand the chemical effect. © 2018, Peking University Press. All right reserved.
dc.description.sponsorshipThe Scientific and Technological Research Council of Turkey (TUBITAK), under the project No. 106T045.
dc.identifier.doi10.3964/j.issn.1000-0593(2018)08-2630-08
dc.identifier.endpage2637
dc.identifier.issn1000-0593
dc.identifier.issue8
dc.identifier.scopus2-s2.0-85092708030
dc.identifier.startpage2630
dc.identifier.urihttps://rdlopen.rawdatalibrary.net/r/ebyu/14174
dc.identifier.volume38
dc.identifier.wosWOS:000443104600051
dc.language.isoen
dc.publisherScience Press
dc.relation.ispartofGuang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectAsymmetry index
dc.subjectChemical effect
dc.subjectRelative intensity ratio
dc.subjectWavelength dispersive X-ray spectroscopy (WDXRF)
dc.subjectRhodium metallography
dc.subjectSingle crystals
dc.subjectSpectrometers
dc.subjectSulfur compounds
dc.subjectTransition metal compounds
dc.subjectTransition metals
dc.subjectX ray spectroscopy
dc.subjectX ray tubes
dc.subject3d transition metals
dc.subjectEnergy shift
dc.subjectLorentz functions
dc.subjectRelative intensity
dc.subjectWavelength dispersive X-ray spectroscopies
dc.subjectX ray fluorescence
dc.subjectChemical analysis
dc.titleChemical Effect Analyses of 3d Elements by Study of X-Ray Fluorescence Spectra
dc.typeArticle
dspace.entity.typePublication
rdl.citation.scopus1
rdl.citation.wos1
rdl.source.indexSCOPUS
rdl.source.indexWOS
rdl.wos.indexScience Citation Index Expanded (SCI-EXPANDED)